Fundamentals of chemical thermodynamicsSyllabus

Subject code

İF-3046y

Credits

9

Student workload

270

Semester

Spring semester

Academic year

2025-2026

Subject type

Mandatory

Form of education

Full-time

Language of instruction

Azerbaijani

In-class hours

a) Mühazirə-30 saat b) Seminar-15 saat c) Laboratoriya - 15 saat

Out-of-class hours

a) TSİ-126 saat b) MRTSİ- 84 saat

The basics of chemical thermodynamics allow us to determine in which direction chemical processes will go, under what conditions they will occur spontaneously, and how favorable they are in terms of energy. the subject, basic concepts and laws of chemical thermodynamics are studied. concepts of thermodynamic system, environment, internal energy, heat, work, enthalpy, entropy and gibbs free energy are explained. the essence of the i, II and III laws of thermodynamics, energy transformations in chemical processes, thermal effects, conditions for spontaneous reactions and their relation to equilibrium are considered. as a result of mastering the subject, students acquire the ability to analyze the energetics of chemical reactions, make calculations using thermodynamic quantities, and apply the laws of thermodynamics to the explanation of chemical processes.

• lecture
• laboratory work
• seminar
• presentations
• teamwork

1. 1

   CLO 1: Explains the basic concepts, laws and principles of chemical thermodynamics.

2. 2

   CLO 2: It applies the concepts of energy, heat, work, enthalpy, entropy and gibbs free energy in thermodynamic systems.

3. 3

   CLO 3: Performs thermodynamic calculations related to chemical equilibrium and phase equilibrium and analyzes the results.

4. 4

   CLO 4: Evaluates the thermodynamic feasibility and efficiency of processes encountered in chemical engineering.

5. 5

   CLO 5: Solves engineering problems using thermodynamic principles in the design and optimization of chemical processes.

6. 6

   CLO 6: It justifies the technological processes occurring in the environment and production fields from a thermodynamic point of view and interprets the obtained results on scientific grounds.

1. 1.
   1. the subject of chemical thermodynamics. laws of thermodynamics - i law of thermodynamicsLecture

   Chemical thermodynamics is a major branch of physical chemistry that studies energy transformations, thermal effects, and equilibrium states of systems during chemical processes. the laws of thermodynamics determine the general regularities of energy exchange and provide conditions for evaluating the possibility of chemical reactions. the first law of thermodynamics is based on the law of conservation of energy and states that the heat given to a system is spent on the change of internal energy and the work done by the system.

   • 1. explains the subject and basic concepts of chemical thermodynamics, distinguishes types of thermodynamic systems and their characteristics.
   • 2. interprets the first law of thermodynamics, explains the relationship between the concepts of internal energy, heat and work, and applies the energy balance equation.
   • 3. analyzes energy transformations in chemical processes, calculates heat effects and energy changes on simple problems using the first law of thermodynamics.
2. 2.
   2. the subject of chemical thermodynamics. laws of thermodynamics - second law of thermodynamicsLecture
3. 3.
   3. the subject of chemical thermodynamics. laws of thermodynamics - III law of thermodynamicsLecture
4. 4.
   4. thermodynamic parameters determination methods - experimental determination methodsLecture
5. 5.
   5. thermodynamic parameters determination methods) - theoretical determination methodsLecture
6. 6.
   6. chemical potential. -partial and integral thermodynamic functions. gibbs-duhem equationLecture
7. 7.
   7. solutions. -thermodynamic and molecular-kinetic conditions of the formation of solutionsLecture
8. 8.
   8. ideal solutions and real solutions - raoult's law and deviations from itLecture
9. 9.
   9. insoluble in each other, liquids with limited solubility. -azeotropic mixtures. distribution law, extractionLecture
10. 10.
    10. alloys. - analytical expressions of thermodynamic functions of formation of alloysLecture
11. 11.
    11. thermodynamics of phase equilibria. physical and chemical analysis. phase transitions. phase order single-component systemsLecture
12. 12.
    12. thermodynamic modeling of phase diagrams. thermodynamic model of liquid (liquidus) and solid phase (solidus) boundariesLecture
13. 13.
    13. processing of ores. determination and modeling of thermodynamic functions of oxidation-reduction processes of ore concentratesLecture
14. 14.
    14. stratification of liquid alloys. - calculation of its limits for high temperatures and pressuresLecture
15. 15.
    15. nanothermodynamics. properties of thermodynamic parameters of nanoparticlesLecture
16. 16.
    1. application of the first law of thermodynamics to chemical reactions. hess's lawSeminar
17. 17.
    2. application of the first law of thermodynamics to chemical reactions. hess's lawSeminar
18. 18.
    3. determining the enthalpy of the reaction based on the temperature dependence of the heat capacitySeminar
19. 19.
    4. solid solutions and intermetallics. typical phase diagrams of their formationSeminar
20. 20.
    5. phase diagrams of azeotropic mixturesSeminar
21. 21.
    6. the main types of phase diagrams. eutectic phase diagrams. phase diagrams with the formation of solid solutions and compoundsSeminar
22. 22.
    7. determination and modeling of thermodynamic functions of oxidation-reduction processes of titanomagnetite ore concentratesSeminar
23. 23.
    8. thermodynamics of obtaining iron glastsSeminar
24. 24.
    1. synthesis of substances. heat capacity of substances. determination of isobaric and isochoric heat capacitiesLaboratory
25. 25.
    2. differential scanning thermal analysisLaboratory
26. 26.
    3. electric motive power methodLaboratory
27. 27.
    4. properties of solutions. cryoscopy and ebuloscopyLaboratory
28. 28.
    5. determination of liquidus in two-component metal alloysLaboratory
29. 29.
    6. determination of crystallization temperatureLaboratory
30. 30.
    The rule of the karagoyunlu and aggoyunlu dynasties in azerbaijanLecture

    The formation of karagoyunlu and aggoyunlu states, management system, foreign and domestic policy are considered. the impact of these states on the development of azerbaijani statehood traditions and their position in regional political processes is highlighted.

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